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Beilstein J. Org. Chem. 2018, 14, 2956–2963, doi:10.3762/bjoc.14.275
Graphical Abstract
Scheme 1: Catalysts studied by DFT calculations.
Scheme 2: Precatalyst initiation in olefin metathesis (L = NHC ligand).
Figure 1: Topographic steric maps (plane xy) of the NHC ligands of species I for the studied SIMes–Ru complex...
Figure 2: Intermediate II for catalysts a) 1 and b) 5 (important bond lengths are given in Å).